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论文编号: O120090114
第一作者所在部门: 904组
中文论文题目: Dynamic Analysis of Elemental Mercury Released from Thermal Decomposition of Coal
英文论文题目: Dynamic Analysis of Elemental Mercury Released from Thermal Decomposition of Coal
论文题目英文:
作者: 郭少青 杨建丽 刘振宇
论文出处:
刊物名称: Energy & Fuels
: 2009
: 23
: 10
: 4817-4821
联系作者: 刘振宇
收录类别:
影响因子: 2.056
摘要: Mercury (Hg) is a toxic and ubiquitous trace element in coal. Monitoring its release behavior during coal processing is a challenging problem. This paper presents a method that is capable of online measurement of the dynamic release behavior of elemental Hg (Hg0) from thermal decomposition of coal. The method couples a temperature-programmed decomposition unit with an atomic fluorescence spectrometry detector (TPD-AFS). The AFS signal can be converted to Hg content for quantitative analysis through calibration. The main advantage of the TPD-AFS system is that it can provide either real-time or accumulated data. It was confirmed that the amount of Hg0 determined by this method agreed well with that by the Ontario-Hydro method, and the results are reproducible with a high accuracy. The method can be used to characterize the release behavior of Hg in coals upon heating and may be used to identify the forms of occurrence of Hg in coals.
英文摘要:
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