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论文编号: O120090111
第一作者所在部门: 904组
中文论文题目: Hydrogenation of heavy liquids from a direct coal liquefaction residue for improved oil yield
英文论文题目: Hydrogenation of heavy liquids from a direct coal liquefaction residue for improved oil yield
论文题目英文:
作者: 李 军 杨建丽 刘振宇
论文出处:
刊物名称: Fuel Processing Technology
: 2009
: 90
: 4
: 490-495
联系作者: 杨建丽
收录类别:
影响因子: 2.066
摘要: For hydrogenation of heavy liquids in direct coal liquefaction residue (DCLR) within the direct coal liquefaction (DCL) process, heavy liquids in a DCLR derived from a bench-scale Shenhua DCL process using Shenhua coal are evaluated under two conditions. One simulates the coal liquefaction conditions of the Shenhua plant in the presence of a Fe-based Shenhua catalyst; the other one simulates the online hydrotreating conditions in the presence of a NiMo/Al2O3 catalyst. The results show that the heavy liquids of DCLR can be hydrogenated under these two conditions yielding less heavy products; hydrogenating the heavy liquids under the online hydrotreating conditions is more effective than that under the coal liquefaction conditions; the preasphaltene fraction is a main problem that yields non-soluble materials under these hydrogenation conditions. The results suggest that hydrogenation of toluene soluble and tetrahydrofuran soluble fractions of the DCLR under the coal liquefaction and online hydrotreating conditions is feasible, but their conversion to lighter products are inapparent under the coal liquefaction conditions, and elimination of the formation of tetrahydrofuran insoluble fraction in the online hydrotreator should be considered.
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