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| 论文编号: |
122214O120110200 |
| 第一作者所在部门: |
609组 |
| 中文论文题目: |
Catalytic performance and characterization of Ni–CaO–ZrO2 catalysts for dry reforming of methane
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| 英文论文题目: |
Catalytic performance and characterization of Ni–CaO–ZrO2 catalysts for dry reforming of methane
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| 论文题目英文: |
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| 作者: |
魏伟
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| 论文出处: |
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| 刊物名称: |
Applied Surface Science
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| 年: |
2011
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| 卷: |
257 |
| 期: |
21 |
| 页: |
9169 |
| 联系作者: |
魏伟 |
| 收录类别: |
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| 影响因子: |
1.795
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| 摘要: |
Ni–CaO–ZrO2 catalysts for CO2 reforming of CH4 were prepared by either co-precipitation or impregnation and characterized by means of N2 adsorption–desorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed (TP) techniques. It was found that the preparation procedure greatly influenced the physicochemical properties of catalysts, such as morphology, phase and surface structure. As a result, their activity in CO2 reforming of CH4 was determined by the dispersion of Ni and the co-precipitated catalysts showed a better stability. Furthermore, CO2-TPD
and transient pulse experiments suggested that the carbon formed over two co-precipitated catalysts was eliminated by different mechanisms, and redox properties and strong basicity were believed to be the key factor for the stability, respectively. |
| 英文摘要: |
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| 外单位作者单位: |
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| 备注: |
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