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论文编号: 122214O120120001
第一作者所在部门: 913组
中文论文题目: A facile approach for synthesis and in situ modification of onion-like carbon with molybdenum carbide
英文论文题目: A facile approach for synthesis and in situ modification of onion-like carbon with molybdenum carbide
论文题目英文:
作者: 杜建平
论文出处:
刊物名称: Physica Status Solidi (A) Applications and Materials
: 2011
: 208
: 4
: 878
联系作者: 杜建平
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摘要: Uniform small onion-like carbon (OLC) modified with molybdenum carbide has been synthesized by a one-step process, using detonation-assisted chemical vapor deposition.The obtained material was characterized by transmission electron microscope, energy-dispersive X-ray spectroscopy,Raman spectroscopy, and X-ray diffraction. The results show that the OLC have almost perfect onion structures containing about 7–10 closed shells and exhibit a narrow distribution of 4–6 nm when the C/Mo ratio is about 150. The hexagonal molybdenum carbide (Mo2C) is dispersed on the surface of OLC. The size of OLC can be controlled by adjusting the C/Mo ratios. The formation mechanism of the nanocomposites of OLC and Mo2C is briefly discussed.
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