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论文编号: 122214O120120025
第一作者所在部门: 909组
中文论文题目: Electrocatalytic performance of Pd nanoparticles supported on SiC nanowires for methanol oxidation in alkaline media
英文论文题目: Electrocatalytic performance of Pd nanoparticles supported on SiC nanowires for methanol oxidation in alkaline media
论文题目英文:
作者: 郭向云
论文出处:
刊物名称: Fuel Cells
: 2011
: 11
: 6
: 907
联系作者: 郭向云
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摘要: Pd nanoparticles (NPs) with a mean size of 10–12 nm are dispersed on the surface of SiC nanowires (NWs) by a cyclic voltammetric deposition method, and employed as an electrocatalyst for methanol oxidation. The high dispersion and small size of supported Pd NPs enable the catalyst to have an electrochemical active surface area of 49.5 m2 g–1, which is larger than that of carbon nanotube supported Pd NPs (38.6 m2 g–1), and that of non-supported Pd NPs (29.9 m2 g–1). Methanol oxidation measurements show that the supported Pd NPs possess a high electrocatalytic activity and an excellent stability. These results indicate that SiC NWs have great potentials as an advantageous supporting material in alcohol fuel cells.
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