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论文编号: 122214O120130253
第一作者所在部门: 103组
中文论文题目:
英文论文题目: Kinetic model of coal-char gasification with steam at elevated pressure
论文题目英文:
作者: 阎琪轩
论文出处:
刊物名称: 30th Annual International Pittsburgh Coal Conference.
: 2013
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摘要: The kinetics of three different ranks of typical Chinese coal chars gasification with steam was investigated at higher pressure (up to 2.0 MPa) in a pressurized fixed bed differential (PFBD) reactor. The results show that the global nth-order rate equation including the only item of steam partial pressure is not appropriate for the gasification in which the total system pressure changes. Thus, in this work, a modified nth-order rate equation was proposed, to be applied for three types of coal-chars including the independent variables (T, yH2O, Ptotal). It is indicated that the effect of steam molar fraction gasification rate is greater than that of the total system pressure. For the three types of coal-chars, the correlation exponent with respect to steam molar fraction decreases with the increase of carbon conversion; however, the carbon conversion has little influence on the correlation exponent with respect to the total system pressure. In addition, as the coal rank increases, the correlation exponent with respect to steam molar fraction and the correlation exponent with the total system pressure increase slightly.
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