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| 论文编号: |
122214O120120378 |
| 第一作者所在部门: |
902组 |
| 中文论文题目: |
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| 英文论文题目: |
Studies on surface impregnation combustion method to prepare supported Co/SiO2 catalysts and its application for Fischer–Tropsch synthesis
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| 论文题目英文: |
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| 作者: |
谭猗生
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| 论文出处: |
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| 刊物名称: |
Applied Catalysis A: General
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| 年: |
2012
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| 卷: |
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| 期: |
435 |
| 页: |
217-224 |
| 联系作者: |
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| 收录类别: |
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| 影响因子: |
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| 摘要: |
A series of supported Co/SiO2 catalysts were prepared by surface impregnation combustion method using cobalt nitrates and citric acid, and the precursors were burnt in different atmospheres. The effects of different calcination atmospheres on the properties of the supported Co/SiO2 catalysts were system-ically studied by TG-DTA, XRD, Raman spectrum, TPR, in situ FTIR, TEM, BET and H2 -chemisorption techniques. The burnt catalyst Cargon-air-reduction which was first burnt in argon and then oxidized in air had about 10 nm Co3 O4 crystalline size, much smaller than that which was directly burnt in air (Co3 O4 size: about 15 nm) and that prepared by conventional impregnation method (Co3 O4 size: about 32 nm) using cobalt nitrate as impregnating solution. Characterizations and FTS results of two other references using different organic cobalt salt aqueous (cobalt acetate and cobalt citrate) as impregnat-ing solution were also added in the supporting information. Comparing with our previously reported Cargon
catalyst directly burnt in the argon atmosphere without further reduction, the influence from surface amorphous carbon and carbonic residues was completely eliminated. The activity of the burnt catalyst Cargon-air-reduction prepared by surface impregnation method was threefold higher than that of the reference CN-reduction prepared by conventional incipient-wetness impregnation method. The surface impregnation combustion method described herein was promising to prepare highly dispersed supported metallic catalysts with smaller particle sizes. |
| 英文摘要: |
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