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论文编号: 122214O120120278
第一作者所在部门: 609组
中文论文题目: Distillation-advances from modeling to applications(刊物名称)
英文论文题目: The Design and Simulation of the Synthesis of Dimethyl Carbonate and the Product Separation Process Plant(章节名称)
论文题目英文:
作者: *王峰
论文出处:
刊物名称: Distillation-advances from modeling to applications
: 2012
:
: 0
: 61-91
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摘要: Dimethyl carbonate (DMC) has become a green and environmental benign chemical due to its multiple reactivity and widely potential usage in chemical industry1. It has been used as a substitute to replace dimethyl sulfate and methyl halides in methylation reactions and as a carbonylation agent to substitute phosgene for the production of polycarbonates and urethane polymers. It also has been evaluated to apply as non-aqueous electrolyte component in lithium rechargeable batteries. Additionally, DMC is a strong contender to help the refining industry meet the Clean Air Act specifications for oxygen in gasoline. DMC has about 3 times the oxygen content as methyl tert-butyl ether (MTBE) and its synthesis is not dependent upon FCU isobutylene yields like MTBE. DMC has a good blending octane (R + M/2 = 105), it does not phase separate in a water stream like some alcohols do, and it is both low in toxicity and quickly biodegradable2.
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