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                                  | 论文编号: | 122214O120120278 |  
                                  | 第一作者所在部门: | 609组 |  
                                  | 中文论文题目: | Distillation-advances from modeling to applications(刊物名称) |  
                                  | 英文论文题目: | The Design and Simulation of the Synthesis of Dimethyl Carbonate and the Product Separation Process Plant(章节名称) |  
                                  | 论文题目英文: |  |  
                                  | 作者: | *王峰 |  
                                  | 论文出处: |  |  
                                  | 刊物名称: | Distillation-advances from modeling to applications |  
                                  | 年: | 2012 |  
                                  | 卷: |  |  
                                  | 期: | 0 |  
                                  | 页: | 61-91 |  
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                                  | 摘要: | Dimethyl carbonate (DMC) has become a green and environmental benign chemical due to
its multiple reactivity and widely potential usage in chemical industry1. It has been used as a
substitute to replace dimethyl sulfate and methyl halides in methylation reactions and as a
carbonylation agent to substitute phosgene for the production of polycarbonates and
urethane polymers. It also has been evaluated to apply as non-aqueous electrolyte
component in lithium rechargeable batteries. Additionally, DMC is a strong contender to
help the refining industry meet the Clean Air Act specifications for oxygen in gasoline.
DMC has about 3 times the oxygen content as methyl tert-butyl ether (MTBE) and its
synthesis is not dependent upon FCU isobutylene yields like MTBE. DMC has a good
blending octane (R + M/2 = 105), it does not phase separate in a water stream like some
alcohols do, and it is both low in toxicity and quickly biodegradable2. |  
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