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| 论文编号: |
122214O120120237 |
| 第一作者所在部门: |
705组 |
| 中文论文题目: |
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| 英文论文题目: |
Preparation of highly-ordered mesoporous carbons by organic-organic self-assembly using the reverse amphiphilic triblock copolymer PPO–PEO–PPO with a long hydrophilic chain
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| 论文题目英文: |
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| 作者: |
*宋燕
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| 论文出处: |
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| 刊物名称: |
Microporous and Mesoporous Materials
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| 年: |
2012
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| 卷: |
159 |
| 期: |
1 |
| 页: |
81-86 |
| 联系作者: |
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| 收录类别: |
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| 影响因子: |
3.285
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| 摘要: |
A family of highly ordered mesoporous carbons (OMCs) were prepared by the organic-organic self-assembly of a reverse amphiphilic triblock copolymer with a soluble in ethanol, low-molecular-molar phenolic resin. The self-assembly was induced by evaporation. Small angle X-ray scattering, transmission electron microscopy and nitrogen adsorption/desorption isotherms evaluated by the Brunauer–Emmett–Teller method have been used to characterize the OMCs. Phase transitions from a lamellar (L∞) one dimensional pore system with pore size centered at 6.3 nm to a hexagonal (p6mm) two dimensional pore system with tunable pore size from 3.5–3.9 nm, to a cubic () three dimensional cagelike pore system with a tri-modal pore structure and finally to another disordered cubic mesoporous carbons, are observed by finely tuning the molar ratios of the phenol/formaldehyde/NaOH/template. All the OMCs had high surface area and a uniform pore size. The results show that by increasing the hydrophilicity of the system by changing the molar ratios of reactants, the mesophase can be tailored conveniently. Furthermore, these transitions help us understand the mechanism of the formation of mesophase to produce different OMCs |
| 英文摘要: |
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| 外单位作者单位: |
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| 备注: |
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关闭窗口 |
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