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论文编号: |
122214O120120147 |
第一作者所在部门: |
704组 |
中文论文题目: |
PEG和PVP改性溶胶-凝胶二氧化硅减反膜的对比
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英文论文题目: |
Comparision of Silica Anti-Reflective Films Obtained via a Sol-Gel Process in the Presence of PEG or PVP
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论文题目英文: |
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作者: |
田红
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论文出处: |
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刊物名称: |
Acta Physico-Chimica Sinica
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年: |
2012
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卷: |
28 |
期: |
5 |
页: |
1197-1205 |
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摘要: |
The different effects of poly(ethylene glycol) (PEG) and poly(vinylpyrrolidone) (PVP) on the structure and laser-induced damage threshold (LIDT) of sol-gel silica anti-reflective films were investigated. The results of dynamic light-scattering, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS) showed that PEG could prompt silica particles to form uniform clusters, whereas in the PVP-modified sol, the growth of silica particles was restricted. This was a result of the strong hydrogen
bonds between Si―OH groups and PVP molecules Multi-fractal spectrum (MFS) analysis suggested that PEG improved the uniformity of the silica film but PVP reduced it, therefore the laser-damage resistance of the PEG-modified silica film was enhanced, but that of the PVP-modified silica film was weakened. 29Si
magic-angle spinning nuclear magnetic responance (MAS NMR) showed that PEG improved the condensation of Si ―O tetrahedron, but PVP did not. This led to differences between the laser-damage resistances of PEG-modified silica films and PVP-modified silica films. |
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