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论文编号: 122214O120120143
第一作者所在部门: 704组
中文论文题目:
英文论文题目: Preparation and Properties of Octadecahedral α-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets
论文题目英文:
作者: 刘忠
论文出处:
刊物名称: European Journal of Inorganic Chemistry
: 2012
: 2012
: 25
: 4076-4081
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摘要: Octadecahedral α-Fe2O3 nanoparticles were hydrothermally synthesized in the presence of formamide. These octadecahedral α-Fe2O3 nanoparticles have a threefold axis and are enclosed by twelve dominant {112} facets and six {104} facets.In comparison with the {104} facets, the sterically less hindered {112} facets induced the selective adsorption of formamide more easily, which resulted in the gradual increase in the amount of {112} facets by decreasing the amount of{104} facets with increasing formamide. The coercivity (Hc) of these octadecahedral particles increased successively as the aspect ratio (c/a) increased. The sensing capability of these particles toward H2O2 was investigated, and the response currents of the particles dominated by {112} facets showed a linear relationship with a concentration of H2O2 in the range from 40 μM to 6.66 mM in different stages.
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