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论文编号: 122214O120120113
第一作者所在部门: 709组
中文论文题目:
英文论文题目: Annealing a graphene oxide film to produce a free standing high conductive graphene film
论文题目英文:
作者: 陈成猛
论文出处:
刊物名称: Carbon
: 2012
: 50
: 2
: 659-667
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影响因子: 5.378
摘要: A free-standing graphene oxide film (GOF) obtained by self-assembly at a liquid/air interface was annealed in a confined space between two stacked substrates to form a free-standing highly conductive graphene film. Characterization indicates that the oxygen-containing functional groups (e.g. epoxy, carboxyl, and carbonyl) were removed as small molecules (e.g. H(2)O, CO(2), and CO) during the annealing, meanwhile the size of sp(2) domains in the film was decreased. When annealed between two stacked wafers, random interlayer expansion and fractional movement in the GOF were suppressed by the pressure-induced friction, which helps preserve the morphology of the film. The conjugation in the basal plane of graphene and pi-pi interactions between well stacked graphene sheets favor the transportation of charge carriers in the film, to produce a good electrical conductivity of the resulting free-standing reduced GOF (increased from 1.26 x 10(-5) to 272.3 S/cm).
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