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论文编号: |
122214O120120111 |
第一作者所在部门: |
902组 |
中文论文题目: |
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英文论文题目: |
Dimethyl Ether Synthesis from CO/CO2/H2 mixtures over CuO-ZnO-Al2O3/γ-Al2O3
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论文题目英文: |
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作者: |
宋法恩
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论文出处: |
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刊物名称: |
29th Annual International Pittsburgh Coal Conference Abstracts Booklet
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年: |
2012
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卷: |
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期: |
0 |
页: |
1-1 |
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摘要: |
The synthesis of dimethyl ether from CO/CO2/H2 mixtures was carried out in a high pressure fixed bed reactor system over CuO-ZnO-Al2O3.The effect of temperature,pressure,space time and time on stream on CO conversion and dimethyl ether selectivity was studied using CO/CO2/H2 mixtures which was composed of (H2)/(CO)/(CO2)/(CH4)=52/24/23/1(V/V).The catalyst samples before and after reaction were characterized by the means of X-ray diffraction(XRD) and nitrogen adsorption.The experimental results indicated that sintering of Cu particles of the catalyst was the main cause of the catalyst deactivation with time on stream. |
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