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论文编号: 122214O120120111
第一作者所在部门: 902组
中文论文题目:
英文论文题目: Dimethyl Ether Synthesis from CO/CO2/H2 mixtures over CuO-ZnO-Al2O3/γ-Al2O3
论文题目英文:
作者: 宋法恩
论文出处:
刊物名称: 29th Annual International Pittsburgh Coal Conference Abstracts Booklet
: 2012
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摘要: The synthesis of dimethyl ether from CO/CO2/H2 mixtures was carried out in a high pressure fixed bed reactor system over CuO-ZnO-Al2O3.The effect of temperature,pressure,space time and time on stream on CO conversion and dimethyl ether selectivity was studied using CO/CO2/H2 mixtures which was composed of (H2)/(CO)/(CO2)/(CH4)=52/24/23/1(V/V).The catalyst samples before and after reaction were characterized by the means of X-ray diffraction(XRD) and nitrogen adsorption.The experimental results indicated that sintering of Cu particles of the catalyst was the main cause of the catalyst deactivation with time on stream.
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