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论文编号: 122214O120120108
第一作者所在部门: 902组
中文论文题目:
英文论文题目: The dimethyl ether synthesis from biomass-derived syngas over CuO-ZnO-Al2O3/γ-Al2O3
论文题目英文:
作者: 宋法恩
论文出处:
刊物名称: International Symposium on Alternative Clean Synthetic Fuel
: 2012
:
: 0
: 291-291
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摘要: The synthesis of dimethyl ether from bimass-deriver syngas was carried out in a high pressure fixed bed reactor system over CuO-ZnO-Al2O3/γ-Al2O3. The effect of temperature, pressure, space time and time on stream on CO conversion and dimethyl ether selectivity was studied using biomass-derived syngas which was composed of (H2)/(CO)/(CO2)/(CH4) = 52/24/23/1 (V/V). The catalyst samples before and after reaction were characterized by the means of X-ray diffraction (XRD) and nitrogen adsorption. The experimental results indicated that sintering of Cu particles of the catalyst was the main cause of the catalyst deactivation with time on stream.
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