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论文编号: 122214O120120098
第一作者所在部门: 702组
中文论文题目: 具有超高比电容的钴镍掺杂的双金属氢氧化物作为超级电容器的电极材料
英文论文题目: CoxNi1?x double hydroxide nanoparticles with ultrahigh specific capacitances as supercapacitor electrode materials
论文题目英文:
作者: 谢莉婧
论文出处:
刊物名称: Electrochimica Acta
: 2012
: 78
: 0
: 205-211
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影响因子: 3.832
摘要: Cobalt nickel double hydroxides (CoxNi1–x LDHs) nanoparticles were synthesized by a polyvinyl pyrrolidone-assisted chemical co-precipitation method. It was found that the ratio between Co and Ni had a significant effect on their electrochemical activities. The speci?c capacitance of 2614 F g?1 was achieved when the atomic ratio of Co to Ni was equal to 0.57: 0.43. This Co0.57Ni0.43 LDH sample had a BET specific surface area of 109.8 m2 g-1 and total pore volume of 0.6036 cm3 g?1 , and its pore size distribution was mainly in the range of 1.5-5 nm, which led to the high liquid–solid interfacial area and further increased the utilization of the active materials. Additionally, the Co0.57Ni0.43 LDH electrode exhibited a good electrochemical stability with 86.4% of the initial capacitance over 1,000 consecutive cycles at 5 A g–1.
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