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论文编号: 122214O120120082
第一作者所在部门: 611组
中文论文题目: Room-temperature synthesis and photocatalytic properties of lepidocrocite by monowavelength visible light irradiation
英文论文题目: Room-temperature synthesis and photocatalytic properties of lepidocrocite by monowavelength visible light irradiation
论文题目英文:
作者: 孙予罕
论文出处:
刊物名称: Journal of Molecular Catalysis A: Chemical
: 2012
: 353
: 0
: 67-73
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摘要: Lepidocrocite was synthesized by aerial oxidation using an FeIIEDTA solution. The synthesis was performed under irradiation from different monowavelength light emitting diode (LED) lamps at room temperature. X-ray diffraction results showed the formation of differently crystallized lepidocrocite. The indirect bandgap values of the lepidocrocite samples were about 2.34, 2.36, and 2.31 eV for red, green, and in a system composed of lepidocrocite, H2O2, and visible light. H2O2 concentration, light irradiation, and catalyst concentration were also investigated. The rate of CV decolorization was found to fit pseudo-firstorder kinetics. The results show that different as-prepared lepidocrocite have different adsorption and photocatalytic characteristics. A possible mechanism was also suggested for the dye degradation.
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