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论文编号: 1222140120150066
第一作者所在部门: 311组
中文论文题目: Aerobic selective oxidation of 5-hydroxymethyl-furfural over nitrogen-doped graphene materials with 2,2,6,6-tetramethylpiperidin-oxyl as cocatalyst
英文论文题目: Aerobic selective oxidation of 5-hydroxymethyl-furfural over nitrogen-doped graphene materials with 2,2,6,6-tetramethylpiperidin-oxyl as cocatalyst
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刊物名称: Catalysis Science Technology
: 2015
:
: 1
: 1-10
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摘要: N-doped graphene materials with various types and quantities of N species were prepared via thermal treatment of graphene oxide in flowing NH3, and their catalytic performance was tested in aerobic selective oxidation of 5-hydroxymethyl-furfural (HMF). A full HMF conversion and nearly 100% selectivity to DFF can be obtained under relatively mild reaction conditions (6 h, 100 °C, 1 atm air pressure) with 2,2,6,6-tetramethylpiperidin-oxyl (TEMPO) as co-catalyst.
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