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论文编号: |
1222140120140360 |
第一作者所在部门: |
707组 |
中文论文题目: |
Silylated Organometals: A Family of Recyclable Homogeneous Catalysts
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英文论文题目: |
Silylated Organometals: A Family of Recyclable Homogeneous Catalysts
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论文题目英文: |
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作者: |
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论文出处: |
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刊物名称: |
Green Chemistry
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年: |
2014
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卷: |
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期: |
0 |
页: |
0-0 |
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影响因子: |
6.85
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摘要: |
A general strategy has been developed to synthesize a family of silylated organometals (M-PPh2-TS and DPEN-Ru-PPh2-Ts, M = Pd2+, Rh+, Pt2+, Ir+, or Ru2+, PPh2-Ts = PPh2CH2CH2Si(OEt)3), DPEN = (1R, 2R)-1, 2-diphenylethylenediamine). They can act as homogeneous catalysts with high efficiencies in various organic reactions using THF, CH2Cl2 or toluene as the reaction medium. After reaction, they could be thoroughly settled down by adding pentane and used repetitively owing to the complete catalyst |
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