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| 论文编号: |
1222140120140317 |
| 第一作者所在部门: |
903组 |
| 中文论文题目: |
Transesterification of dimethyl carbonate with tetrahydrofurfuryl alcohol on the K2CO3/ZrO2 catalyst—Function of the surface carboxylate species
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| 英文论文题目: |
Transesterification of dimethyl carbonate with tetrahydrofurfuryl alcohol on the K2CO3/ZrO2 catalyst—Function of the surface carboxylate species
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| 论文题目英文: |
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| 作者: |
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| 论文出处: |
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| 刊物名称: |
Applied Catalysis B: Environmental
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| 年: |
2014
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| 卷: |
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| 期: |
152 |
| 页: |
226-232 |
| 联系作者: |
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| 收录类别: |
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| 影响因子: |
6.423
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| 摘要: |
An efficient and selective synthesis of unsymmetrical tetrahydrofurfuryl carbonate and other organic carbonates was realized in the liquid phase transesterification dimethyl carbonate (DMC) with alcohols over the K2CO3/ZrO2 catalyst. Compared with MgO, CaO, MgAl-HDT, ZrO2, and CsF/α-Al2O3, the K2CO3/ZrO2 catalyst with lower basicity displayed a significantly higher activity. The results of FT-IR, XPS and CO2-TPD suggested that the carboxylate species on the surface of the K2CO3/ZrO2 catalyst wer |
| 英文摘要: |
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| 备注: |
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